SYNTHESIS OF HAGOGENCONTAINING COMPOUNDS BASED ON MONO- AND DIAMINES
Abstract
In this work the synthesis of monoamines on the base of acetylene amino- alcohols and diamines in the presence of acetylene, paraform and secondary ami-nes by the Mannich reaction.was inivestigated. The structure, physico-chemical culconstants and conditions of formation of synthesized monoamines and diamines with high yields have been determined. In the molecules of monoamines and diamines there are chemically active centers: -C ≡ C-, atom –N= and -C ≡ C - H. The reactions halogenation of triple bond by halogenated acids and the formation of a quaternary salts have been studied. The structure of the synthesized products was confirmed by IR and PMR spectrums. Their physico-chemical constants and yields have been determined. Dependence of the products yield on the nature of the used catalysts was determined.
Keywords
3-N-dimethylaminopropine -1, 3-N-diethylaminopropyne-1, 1,4-di (N,N-dimethylamino) butyne -2How to Cite
Downloads
References
Azerbaev I.N., Sarbaev T.T. Chemistry regulates plant growth. Alma-Ata: Nauka, 1966. - P. 8.
Atavin A.T., Dmitrieva Z.T., Trofimov B.A. Biologically active compounds, - L .: Science. 1968 .-- P. 113
Herbicidal activity of derivatives of acetylenic alcohols Sirlibaev T.S., Kurbanov A.I., Turgunov E., Kultaev K.K., Koblov R.K., Khikmatov A., Agrochemistry. 1985, No. 11. - C.105-107.
Biological activity of some acetylenic aminoalcohols and halogen-containing products based on them A.I. Kurbanov, T.S. Sirlibaev, E. Turgunov, K.K. Kultaev, R.K. Kovlov, S. Tarikov. Agrochemistry, 1986, No. 4. -P. 86 -89
Fudsuki Sun. J. Chem. Soc. Jap., Pure Chem. See. Synthesis of acetylenic amines. RZhKhim., 1967, 2Zh146.
Biel J.H. N-alkylpiperidyl alkynyl amines. RZhKhim., 1960, 93528P.
Kotlyarovsky I. JI ,. Andrievskaya E.K. Mono and diamines, derivatives of p-diethynylbenzene. Izv. Academy of Sciences of USSR. Ser. chem. 1966. No.3. - P. 546-549.
Lisker I.S. Physical methods of investigations in agromonitoring. Physical methods and means of obtaining information in agromonitoring.- L.1987.- P.3-21.
Kurbanov A.I., Sirlibaev T.S., Kultaev K.K. Halogenation and hydrohalogenation of some acetylenic amino alcohols. J.of Applied Chemistry. 1985, No. 11. - P. 2583 - 2586
Petrov A.A., Balyan Ch.V., Trenko A.T. Organic Chemistry, Higher School Publishing House, - Moscow, 1968, - P. 614-615
Copyright (c) 2024 Kuzibay Kultaev (Author)
This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors retain the copyright of their manuscripts, and all Open Access articles are disseminated under the terms of the Creative Commons Attribution License 4.0 (CC-BY), which licenses unrestricted use, distribution, and reproduction in any medium, provided that the original work is appropriately cited. The use of general descriptive names, trade names, trademarks, and so forth in this publication, even if not specifically identified, does not imply that these names are not protected by the relevant laws and regulations.
