Open Access

Effect of CO₂ Corrosion Inhibitor on Phase Separation Efficiency in Gas Condensate Processing and Justification for Demulsifier Application

4 Project consultant, South Stream Transport B.V. Istanbul, Türkiye

Abstract

The article examines the effect of a carbon dioxide corrosion inhibitor on phase-separation efficiency during gas-condensate processing and substantiates the use of a demulsifier within a multifunctional reagent formulation. The study's relevance lies in the contradiction between the need to protect field infrastructure from CO₂ corrosion and the requirement for stable separation of the water-methanol and hydrocarbon phases under the complex thermobaric conditions of gas condensate fields. The aim of the study is to assess the effect of an imidazoline inhibitor on emulsion stability and to develop a solution that preserves anticorrosion protection while restoring phase separation. The scientific novelty lies in identifying a nonlinear relationship between inhibitor concentration and separation quality, as well as in demonstrating the synergy between a polyol demulsifier and hydrodynamic modernization of buffer vessels. It was established that the base inhibitor intensifies emulsion stabilization and carryover of the water-methanol solution, whereas the polyol additive and apparatus modernization restore phase separation even at extreme reagent concentrations. The article may be useful for researchers, process engineers, specialists in gas and condensate treatment, and field corrosion protection services.

Keywords

References

Adambekova, A., Kozhagulov, S., Salnikov, V., Quadrado, J. C., Polyakova, S., Salimbayeva, R., Rysmagambetova, A., Musralinova, G., & Tanybayeva, A. (2025). ESG Practices and Air Emissions Reduction in the Oil and Gas Industry: Empirical Evidence from Kazakhstan. Sustainability, 17(24), 11317. https://doi.org/10.3390/su172411317
Ahmadi, S., & Khormali, A. (2025). Petroleum Emulsion Stability and Separation Strategies: A Comprehensive Review. ChemEngineering, 9(5), 113. https://doi.org/10.3390/chemengineering9050113
Askari, M., Aliofkhazraei, M., Jafari, R., Hamghalam, P., & Hajizadeh, A. (2021). Downhole corrosion inhibitors for oil and gas production – a review. Applied Surface Science Advances, 6, 100128. https://doi.org/10.1016/j.apsadv.2021.100128
Bohnsack, D., Potten, M., Freitag, S., Einsiedl, F., & Zosseder, K. (2021). Stress sensitivity of porosity and permeability under varying hydrostatic stress conditions for different carbonate rock types of the geothermal Malm reservoir in Southern Germany. Geothermal Energy, 9, 15. https://doi.org/10.1186/s40517-021-00197-w
Chauhan, D. S., Quraishi, M. A., & Qurashi, A. (2021). Recent trends in environmentally sustainable Sweet corrosion inhibitors. Journal of Molecular Liquids, 326, 115117. https://doi.org/10.1016/j.molliq.2020.115117
Dong, B., Qin, Z., Wang, Y., Zhang, J., Xu, Z., Liu, A., & Guo, X. (2022). Investigating the Rheology and Stability of Heavy Crude Oil-in-Water Emulsions Using APG08 Emulsifiers. ACS Omega, 7(42), 37736–37747. https://doi.org/10.1021/acsomega.2c04684
Gurjar, S., Sharma, S. K., Sharma, A., & Ratnani, S. (2021). Performance of imidazolium based ionic liquids as corrosion inhibitors in acidic medium: A review. Applied Surface Science Advances, 6, 100170. https://doi.org/10.1016/j.apsadv.2021.100170
Iakhin, I. (2025). Adaptive Renovation of Centrifugal Separators: A Computational–Experimental Methodology for Optimizing Gas-Dynamic Regimes without Capital Expenditure. Universal Library of Innovative Research and Studies, 02(04), 111–119. https://doi.org/10.70315/uloap.ulirs.2025.0204019
Iakhin, I. (2026a). Analysis of Liquid Carryover Causes in Gas Separation Equipment and Modern Approaches to Minimization. International Journal of Scientific Engineering and Science, 74–77. http://ijses.com/wp-content/uploads/2026/01/48-IJSES-V10N1.pdf
Iakhin, I. (2026b). Theoretical Foundations of Gas-Dynamic Processes in Centrifugal Separators under Variable Flow Regimes. Australian Journal of Engineering and Innovative Technology, 276. https://doi.org/10.34104/ajeit.026.02760282
Jin, Y., Liu, D., & Hu, J. (2021). Effect of Surfactant Molecular Structure on Emulsion Stability Investigated by Interfacial Dilatational Rheology. Polymers, 13(7), 1127. https://doi.org/10.3390/polym13071127
Klimov, M., Ramazanov, R., Husein, N., Upadhye, V., Drobot, A., Bydzan, A., & Gazizov, R. (2022). Dynamic Production Surveillance Method Effect in a Gas Condensate Horizontal Wells. 2022 International Petroleum Technology Conference, IPTC-22261-MS. https://doi.org/10.2523/iptc-22261-ms
Kryukov, V., & Tokarev, A. (2023). Hard-to-recover oil reserves in the context of sustainable development of resource regions. E3S Web of Conferences, 470, 01026. https://doi.org/10.1051/e3sconf/202347001026
Li, S., Du, T., Cui, G., He, H., Wu, P., & Li, Y. (2024). Inhibition Localized Corrosion of N80 Petroleum Pipeline Steel in NaCl-Na2S Solution Using an Imidazoline Quaternary Ammonium Salt. Processes, 12(3), 491. https://doi.org/10.3390/pr12030491
MalekiZadeh, R., Hosseini, S., & Narimani, M. (2025). Investigation on the adsorption and surface activity of imidazolium chloride-based ionic liquids; resin and asphaltene synthetic oil and high salinity. Journal of Petroleum Exploration and Production Technology, 15(9). https://doi.org/10.1007/s13202-025-02037-0
Rongtao, L., Xinwei, L., Jiandong, Z., Changwang, G., Dongfeng, Z., Yuandong, Z., & Xingze, Z. (2021). Asphaltene Deposition during CO2 Flooding in Ultralow Permeability Reservoirs: A Case Study from Changqing Oil Field. Geofluids, 2021(1), 6626114. https://doi.org/10.1155/2021/6626114
Sriplai, N., & Sombatmankhong, K. (2023). Corrosion inhibition by imidazoline and imidazoline derivatives: a review. Corrosion Reviews, 41(3). https://doi.org/10.1515/corrrev-2022-0092
Tian, Y., Zhou, J., He, C., He, L., Li, X., & Sui, H. (2022). The Formation, Stabilization and Separation of Oil–Water Emulsions: A Review. Processes, 10(4), 738. https://doi.org/10.3390/pr10040738
Wang, Z. M., Song, G.-L., & Zhang, J. (2019). Corrosion Control in CO2 Enhanced Oil Recovery From a Perspective of Multiphase Fluids. Frontiers in Materials, 6. https://doi.org/10.3389/fmats.2019.00272
Yalamov, D., Georgiev, P., & Garbatov, Y. (2023). Economic Feasibility of Retrofitting an Ageing Ship to Improve the Environmental Footprint. Applied Sciences, 13(2), 1199. https://doi.org/10.3390/app13021199
Yang, L., Chen, X., Huang, C., Liu, S., Ning, B., & Wang, K. (2024). A review of gas-liquid separation technologies: Separation mechanism, application scope, research status, and development prospects: Chemical Engineering Research & Design: Transactions of the Institution of Chemical Engineers Part A. Chemical Engineering Research & Design: Transactions of the Institution of Chemical Engineers Part A, 201, 257–274. https://doi.org/10.1016/j.cherd.2023.11.057
Yao, L., Shi, H., Qi, W., Song, B., Zhou, J., Sun, W., & Sun, Y. (2026). A Review of Oil–Water Separation Technology for Transformer Oil Leakage Wastewater. Water, 18(2), 180. https://doi.org/10.3390/w18020180

Most read articles by the same author(s)

Similar Articles

You may also start an advanced similarity search for this article.